bims-cytox1 Biomed News
on Cytochrome oxidase subunit 1
Issue of 2025–07–20
three papers selected by
Gavin McStay, Liverpool John Moores University



  1. bioRxiv. 2025 Jun 16. pii: 2025.06.11.659066. [Epub ahead of print]
      Copper (Cu) is an essential trace element required for mitochondrial respiration via its incorporation into cytochrome c oxidase (CuCOX), the terminal enzyme of the electron transport chain. In this study, we employed size-exclusion chromatography coupled with inductively coupled plasma mass spectrometry (SEC-ICP-MS), UV-Vis spectroscopy, and immunoblotting to identify and validate a high-molecular-weight Cu-containing peak in SEC-ICP-MS chromatogram as representative of CuCOX activity. We demonstrate that this CuCOX peak is enhanced under metabolic conditions favoring oxidative phosphorylation, such as high Cu supplementation or galactose-containing media, and correlates with increased mitochondrial respiration. By tracing exogenously supplied 63Cu, we characterized the time- and dose-dependent incorporation of newly acquired Cu into CuCOX. Functional RNA interference (RNAi) experiments targeting key Cu transporters revealed that CuCOX formation is independent of the high-affinity Cu importer CTR1, but instead relies on alternative transporters including DMT1, LAT1, and the mitochondrial carrier SLC25A3. These findings offer new insight into the cellular pathways governing Cu trafficking and allocation to mitochondria under physiologically relevant conditions. Furthermore, our work establishes SEC-ICP-MS as a sensitive and specific method for quantifying CuCOX and assessing mitochondrial metabolism. This platform holds promise for the identification of Cu-related biomarkers and therapeutic targets, particularly in the context of diseases such as renal cell carcinoma (RCC), where dysregulated Cu homeostasis plays a critical role.
    DOI:  https://doi.org/10.1101/2025.06.11.659066
  2. Hum Mol Genet. 2025 Jul 18. pii: ddaf123. [Epub ahead of print]
      SCO1 is a nuclear-encoded protein with roles in cytochrome c oxidase (COX) assembly and the regulation of copper homeostasis. It remains unclear, however, why mutations in this ubiquitously expressed gene product cause distinct, tissue-specific forms of disease that primarily affect heart, liver or brain function. To gain a better understanding of the clinical heterogeneity observed across SCO1 pedigrees, we deleted Sco1 in the murine brain and observed a severe COX deficiency in the absence of altered tissue copper content that was tied to early, neonatal lethality. We therefore transitioned to whole body knockin mice expressing allelic variants of SCO1 that are pathogenic in humans to more accurately reflect the patient condition and avoid the lethality associated with tissue-specific Sco1 knockout. Sco1M277V mice exhibited the most severe COX deficiency in their brain, modeling the pathophysiological consequences of the p.Met294Val variant in humans and supporting the idea that the primary role of SCO1 in this tissue is to promote COX assembly. Phenotyping of Sco1G115S, Sco1P157L and Sco1M277V mice nonetheless emphasized that the heart generally displayed the most severe, combined COX and copper deficiency, with Sco1G115S and Sco1P157L hearts developing a dilated cardiomyopathy that was accompanied by significant depletion of their mitochondrial copper pool. Taken together, our findings suggest that in an isogenic context the heart is the most susceptible organ to loss of SCO1 function, and that single nucleotide polymorphisms at modifier loci in an outbred population likely contribute to the clinical heterogeneity observed across SCO1 pedigrees.
    Keywords:  Cytochrome c oxidase; SCO1; copper; mitochondrial disease
    DOI:  https://doi.org/10.1093/hmg/ddaf123
  3. Int J Hematol. 2025 Jul 14.
      Copper deficiency can lead to anemia, leukopenia, or thrombocytopenia, often mimicking vitamin B12 deficiency or myelodysplastic syndrome. We review the crucial role of copper in iron metabolism and hematopoiesis, highlighting how high-dose zinc supplementation, gastrointestinal surgeries, and long-term nutritional support can induce deficiency. The pathophysiology involves compromised ferroxidase activity, which hampers iron utilization, and reduced neutrophil survival due to impairment of cytochrome c oxidase and superoxide dismutase. Timely recognition is vital, as most cases respond to copper repletion and zinc reduction. Institutional data underscore the need for routine copper monitoring, and management strategies aim to optimize patient care by maintaining adequate copper levels.
    Keywords:  Anemia; Ceruloplasmin; Copper deficiency; Enteral nutrition; Zinc
    DOI:  https://doi.org/10.1007/s12185-025-04036-7